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Название Studying the impact of alkaline sulfide leaching parameters upon the efficiency of arsenic recovery from copper skimmings of lead production
DOI 10.17580/nfm.2020.02.03
Автор Tymbayeva A. A., Mamyachenkov S. V., Bannikova S. A., Anisimova O. S.
Информация об авторе

D. Serikbayev East Kazakhstan State Technical University, Ust-Kamenogorsk, Republic of Kazakhstan1; Kazzinc Ltd., Ust-Kamenogorsk, Republic of Kazakhstan2:

A. A. Tymbayeva, PhD Student1, Chief Specialist at the Research Center of Ust-Kamenogorsk Metallurgical Complex2, e-mail: aigerimnabiyeva92@gmail.com

 

Ural Federal University named after the First President of Russia B. N. Yeltsin, Yekaterinburg, Russian Federation:
S. V. Mamyachenkov, Professor, Head of the Department of Non-Ferrous Metals Metallurgy, e-mail: svmamyachenkov@yandex.ru

O. S. Anisimova, Associate Professor at the Department of Non-Ferrous Metals Metallurgy

 

Kazzinc Ltd., Ust-Kamenogorsk, Republic of Kazakhstan.
S. A. Bannikova, Head of the Research Center of Ust-Kamenogorsk Metallurgical Complex, e-mail: sbannikova@kazzinc.com

Реферат

The article is concerned with the problem of arsenic circulation as copper skimmings of lead production — the product of the lead bullion decopperization process at a metallurgical complex, uniting copper and lead plants. A brief overview of the methods of processing arsenic-containing middling products for the purpose of arsenic removal is given; the main advantages and disadvantages are indicated. The possibility of processing copper skimmings by the method of alkaline sulfide leaching with separation into arseniccontaining solution and lead-copper precipitate is studied. The results of the researches into the influence of temperature, process duration, solids content in the pulp, particle size, and the ratio of sodium hydroxide to elemental sulfur in the alkaline sulfide reagent on the process of alkaline sulfide leaching of copper skimmings af lead production are provided. Within the studied range of varied factors, the highest indexes of arsenic extraction into solution (85.04%) were achieved under the following conditions: temperature — 85 °C, duration — 4 hours, solids content in the pulp — 350 g/dm3, fraction (–0.08 mm), NaOH/S ratio = 100 g/100 g in 1 dm3 of the solution. The proposed method for processing copper skimmings will allow one to selectively isolate arsenic into the dump waste product during subsequent precipitation and separate contaminant from lead-copper cake, into which precious metals also pass. Such an approach provides the reduction of arsenic circulation between the lead and copper manufacturing facilities.

Ключевые слова Arsenic, alkaline sulfide leaching, copper skimmings of lead production, hydrometallurgical processing, sodium polysulphides, arsenic-containing middling products, sodium hydroxide, copper-lead cake
Библиографический список

1. Nabiyeva A. A., Kulenova N. A. Review of Domestic Basis of Non-Ferrous Industry: Problems of Complex Processing of Polymetallic Raw Materials with a High Level of Impuritites. Innovations in the Field of Natural Sciences as the Basis for the Export-Oriented Industrialization of Kazakhstan: Materials of the Scientific and Practical Conference Dedicated to the 10-year Kazakhstan National Academy of Natural Sciences and the 25th Anniversary of International Central Integrated Processing Mineral Raw Materials of the Republic of Kazakhstan. Almaty: RSE “NC KPMS RK”, 2019. pp. 393–396.
2. Rtskhiladze V. G. Arsenic. Moscow: Izdatelstvo “Metallurgiya”, 1969. 189 p.
3. Sedelnikova G. V., Kurkov A. V., Smirnov K. M. Autoclave Oxidation of Refractory Gold-Sulfide Concentrates in Russian Federation. Theory and Practice of Recent Five Years. Tsvetnye Metally. 2016. No. 8. pp. 25–32. DOI: 10.17580/tsm.2016.08.03
4. Isabaev S. M., Kuzgibekova Kh. M., Zikanova T. A., Zhinova E. V. Complex Hydrometallurgical Processing of Lead Arsenic-Containing Dust from Copper Production. Tsvetnye Metally. 2017. No. 8. pp. 33–37. DOI: 10.17580/tsm.2017.08.04
5. Naboychenko S. S., Mamyachenkov S. V., Karelov S. V. Arsenic in Nonferrous Metallurgy. Ekaterinburg: UrO RAN, 2004. 238 p.
6. Kopylov N. I., Kaminsky Yu. D. Arsenic. Novosibirsk: Sibirskoe Universitetskoe Izdatelstvo, 2004. 367 p.
7. Anderson C. G., Twidwell L. G. The Alkaline Sulfide Hydrometallurgical Separation, Recovery and Fixation of Tin, Arsenic, Antimony, Mercury and Gold. SAIMM. Lead and Zinc. 2008. pp. 121–132.
8. Anderson C. G. The Treatment of Arsenic Bearing Ores, Concentrates and Materials with Alkaline Sulfide Hydrometallurgy. Arsenic Metallurgy: Fundamentals and Applications. TMS. 2005. pp. 255–263.
9. Anderson C. G. Alkaline sulfide leaching technology; just the facts. Proceedings Of The 7th International Symposium. Hydrometallurgy. 2014. Vol. 1. pp. 77–88.
10. Ponomareva E. I., Solovyeva V. D., Bobrova V. V. Arsenic in Lead-Zinc And Copper Industry. Kompleksnoye Ispolzovanie Mineralnogo Syriya. Vestnik AN KazSSR. 1978. pp. 66–71.
11. Amir Mohammad Nazari, Rebecca Radzinski, Ahmad Ghahreman. Review of Arsenic Metallurgy: Treatment of Arsenical Minerals and the Immobilization of Arsenic. Hydrometallurgy. 2017. Vol. 174. pp. 258–281.
12. Malyshev V. P. Probabilistic-Deterministic Experiment Planning. Alma-Ata: Science of the Kazakh SSR, 1981. 116 p.
13. Liu Z.-X., Sun L., Tang L.-D., Hu J., Xiao Y., Chen Y.-G., Yin Z.-L. Removal of Metallic Impurities from Off-Grade Copper Concentrate in Alkaline Solution. International Journal of Nonferrous Metallurgy. Vol. 7, Iss. 2. 2018. pp. 9–23.

Полный текст статьи Studying the impact of alkaline sulfide leaching parameters upon the efficiency of arsenic recovery from copper skimmings of lead production
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