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Power Engineering and Ecology
ArticleName On possibility of the use of metallurgical production wastes as a sorbent in the industrial water cycle
ArticleAuthor M. A. Sulimova, V. M. Sizyakov, T. E. Litvinova, V. V. Vasilyev
ArticleAuthorData

St. Petersburg Mining University (St. Petersburg, Russia):

Sulimova M. A., Leading Engineer, Laboratory of Theoretical and Applied Chemistry, e-mail: wwlog@ya.ru
Sizyakov V. M., Dr. Eng., Prof., Chair of Metallurgy
Litvinova T. E., Dr. Eng., Ass. Prof., Chair of General and Physical Chemistry, e-mail: viritsa@mail.ru
Vasilyev V. V., Cand. Eng., Ass. Prof., Chair of Metallurgy, e-mail: vovchegv@mail.ru

Abstract

Possibility of the use of ferromanganese nodules from the Finnish Gulf for sewage treatment at the enterprises of mineral and raw material complex was proved in this paper. The main examples of polluting of waste water by various plants of metallurgical industry with phenols and cyanide compounds are shown. Ferromanganese nodules were studied by the methods of synchronic thermal analysis and Raman spectroscopy. Structure and phase composition of ferromanganese nodules from Finnish Gulf were examined in details. Existence of iron oxide (III) and manganese oxide (IV) in amorphous and semi-amorphous form in these nodules was established, and it distinguishes the structure of ferromanganese nodules from the Finnish Gulf in comparison with oceanic nodules; it also stipulates their high sorption activity regarding to organic substances. Various adsorption mechanism of phenols, cyanide compounds (including their catalytic oxidation on the surface of ferromanganese nodules) and cations of ferrous and heavy non-ferrous metals aloows to provide cleaning of waste water with removal of organic and inorganic impurities as a single process. The kinetic equations of sorption of phenols and cyanide compounds for ferromanganese nodules were obtained. It was also established that cleaning of waste is based on their sorption ability. Thereby, waste water cleaning by ion exchange mechanism can be performed in parallel with the sorption mechanism. The principal schematic diagram of the adsorption unit for waste water cleaning is presented.

keywords Ferromanganese nodules, sorbents, waste water, metallurgical wastes, sorption, adsorption mechanism, phenols, cyanide compounds
References

1. Sizyakov V. M., Bazhin V. Yu., Selishcheva T. A., Vlasov A. A. Rol gosudarstva v oblasti innovatsionnoy deyatelnosti predpriyatiy tsvetnoy metallurgii Rossii (The role of the State in the field of innovation of enterprises in non-ferrous metallurgy of Russia). Metallurg = Metallurgist. 2014. No. 1. pp. 4–7.
2. Aksenov V. I. Zamknutye sistemy vodnogo khozyaystva metallurgicheskikh predpriyatiy (Closed systems of water industry of metallurgical enterprises). Moscow : Metallurgiya, 1991.
3. Aksenov V. I., Ladygichev M. G., Nichkova I. I., Nikulin V. A., Klyayn S. E., Aksenov E. V. Vodnoe khozyaystvo promyshlennykh predpriyatiy. Spravochnoe izdanie: v 2-kh knigakh (Water industry of industrial enterprises. Reference book in two volumes). Moscow : Teplotekhnik, 2005. 640 p.
4. Veeresh G. S., Kumar P., Mehrota L. Treatment of phenol and cresols in upflow anaerobic sludge blanket (UASB) process: a review. Water Research. 2005. Vol. 39. p. 154.
5. Metcalf L., Eddy H. Wastewater Engineering—Treatment and Reuse, fourth ed., McGraw-Hill International Edition, USA, 2004.
6. Cheremisina O. V., Sulimova M. A., Chirkst D. E. Kinetika okisleniya fenola pirolyuzitsoderzhashchimi mineralami (Kinetic oxidation of phenol by piroluzit containing minerals). Zapiski Gornogo instituta = Proceedings of the Mining Institute. 2013. Vol. 202. pp. 224–227.
7. Chirkst D. E., Cheremisina O. V., Ivanov M. V. et al. Sorbtsiya zheleza (2+) zhelezomargantsevymi konkretsiyami (Sorption of Iron(II) on Ferromanganese Nodules). Zhurnal Prikladnoy Khimii = Russian Journal of Applied Chemistry. 2005. Vol. 78, No. 4. pp. 599–605.
8. Chirkst D. E., Cheremisina O. V., Ivanov M. V., Chistyakov A. A., Zhadovskiy I. T. Izoterma obmena kationov natriya i medi na zhelezomargantsevykh konkretsiyakh (Isotherm of exchange of sodium and copper cations on ferrimanganese concretions). Zhurnal Prikladnoy Khimii = Russian Journal of Applied Chemistry. 2009. Vol. 82, Iss. 2. pp. 238–242.
9. Cheremisina O. V., Chirkst D. E., Sulimova M. A. Kinetika okisleniya fenola zhelezomargantsevymi konkretsiyami (Kinetics of oxidation of phenol by iron-manganese concretions). Zhurnal obshchey khimii = Russian Journal of General Chemistry. 2012. Vol. 82, Iss. 4. pp. 599–606
10. Cheremisina O. V., Sulimova M. A., Chirkst D. E. Kinetika okisleniya geksatsianoferrata (III) pirolyuzitom (Kinetics of the oxidation of hexacyanoferrate(III) with pyrolusite). Zhurnal fizicheskoy khimii = Russian Journal of Physical Chemistry A. 2013. Vol. 87, No. 6. pp. 937–940.
11. Sulimova M. A., Litvinova T. E., Lutskii D. S., Cheremsina O. V. The application of ferromanganese concretions (FMC) to clean industrial drains from phenol and its derivatives. FOG Freiberg Online Geoscience. 2015. Vol. 40. pp. 103–108.
12. Lure Yu. Yu. Analiticheskaya khimiya promyshlennykh stochnykh vod : Monografiya (Analytical chemistry of industrial waste waters : monograph). Moscow : Khimiya, 1984. 448 p.
13. Metodika LYuMEKS vypolneniya izmereniy massovoy kontsentratsii fenolov v probakh pitevykh, prirodnykh i stochnykh vod fl uorimetricheskim metodom na analizatore zhidkosti «Flyuorat-02» (Method LUMEX for measurements of mass concentration of phenols in the samples of potable, natural and waste waters by fl uorimetry method on liquid analyzer “Fluorat-02”). Moscow : LLC “Lumex”, 2007. (in Russian)
14. Gigienicheskie normativy GN 2.1.5.1315-03. Predelno dopustimye kontsentratsii (PDK) khimicheskikh veshchestv v vode vodnykh obektov khozyaystvenno-pitevogo i kulturno-bytovogo vodopolzovaniya (Hygyenic regulations GN 2.1.5.1315-03. Maximum permissible concentrations of chemical substances in water of water objects of household water and community water consumption). Information-publishing center of the Public Health Ministry of Russia, 2001. (in Russian)
15. GOST 22772.3-96. Rudy margantsevye, kontsentraty i aglomeraty. Metody opredeleniya dvuokisi margantsa (State Standard 22772.3-96. Manganese ores, concentrates and agglomerates. Methods for determination of manganese dioxide). Interstate Council on Standartization, Metrology and Certification, 1996. (in Russian)
16. ISO 4297-78. Rudy margantsevye, kontsentraty i aglomeraty. Obshchie trebovaniya k metodam khimicheskogo analiza (ISO 4297-78. Manganese ores, concentrates and agglomerates. Gene ral requirements for methods of chemical analysis). Moscow : Publishing House of Standards, 1998. (in Russian)
17. Otchet po issledovaniyam «Obemy morskikh poiskovo-otsenochnykh rabot obshchestva s ogranichennoy otvetstvennostyu «Petrotrans» za 2003-2007 gody (Report about the investigations “Volumes of marine searching-estimation works of the LLC “Petrotrans” for the period of 2003-2007). St. Petersburg. LLC “Diomar”, 2007. (in Russian)
18. Mehrotra A., Kundu K., Sreekrishnan T. R., Decontamination of heavy metal laden sewage sludge with simultaneous solids reduction using thermophilic sulfur and ferrous oxidizing species. Journal of Environmental Management. 2016. Vol. 167, February 01. pp. 228–235.
19. Chen C.-F., Binh N. T., Chen C.-W. et al. Removal of polycyclic aromatic hydrocarbons from sediments using sodium persulfate activated by temperature and nanoscale zero-valent iron. Journal of the Air and Waste Management Association. 2015. Vol. 65, Iss. 4. pp. 375–383.
20. Golik V., Komashchenko V., Morkun V. Innovative technologies of metal extraction from the ore processing mill tailings and their integrated use. Metallurgical and Mining Industry. 2015. Vol. 7, Iss. 3. pp. 49–52.
21. Shadrunova, I. V., Orekhova, N. N. A Process for Advanced Recycling of Water Originating from Mining Operations, with Metal Recovery. Mine Water and the Environment. 2015. Vol. 34, Iss. 4. pp. 478–484.
22. Yu X., Xu R., Wei C., Wu H. Removal of cyanide compounds from coking wastewater by ferrous sulfate: Improvement of biodegradability. Journal of Hazardous Materials. 2016. Vol. 302. pp. 468–474.

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